Repository Universitas Pakuan

Detail Karya Ilmiah Dosen

Sawarni Hasibuan, Hermawan

Judul : Scaling up Model for Developing Second-Generation (2G) Bioethanol by using Palm Empty Fruit Bunches Feedstock

Abstrak :
As the country with the largest palm oil production in the world, the potential of lignocellulose waste like an empty fruit bunch produced by Indonesia is huge. Utilization of empty fruit bunch feedstock into second-generation (2G) bioethanol on a pilot scale is quite extensive. 2G bioethanol is also generally recognized as a promising market potential because of its less impact on the environment, however, the production cost is still rather high and the development of a commercially competitive process for 2G technology poses a challenge. This research attempts to investigate the model of scaling up of 2G bioethanol production to accelerate commercialization by integrating the well-established sucrose-tobioethanol process from palm oil lignocellulose feedstock. The case of scaling up to be calculated for a chemical pathway of bioethanol production with productivity consideration. Scaling up shows some of the unit process shall complete the basic step in laboratories scale. The supporting process must develop in pretreatment step likes empty fruit bunch washing, drying, and mechanical tearing. The additional process in hydrolysis step is filtering and evaporation glucose liquor until appropriate concentration. The distillation step develops for industrial scale according to alternatives products such as ethanol for solvent, pharmaceutical grade ethanol, or biofuels. The industrial-scale model estimate to produce 18.6 KL/days of bioethanol (ethanol content of 99.6%) need to support at least three crude palm oil plant with capacities 30-45 ton empty fruit bunch feedstock/hour. The model calculated empty fruit bunch feedstock about 600 ton/day.

Tahun : 2018 Media Publikasi : Seminar Internasional

Kategori : Prosiding No/Vol/Tahun : - / - / 2018

ISSN/ISBN : 2169-8767

PTN/S : Universitas MercuBuana Jakarta dan Universitas Pakuan Bogor Program Studi : ILMU KOMPUTER

Bibliography :
Abdul Khalil, H.P.S., Poh, B.T., Jawaid, M., Ridzuan, R., Said, M.R., Achmad, F., and Fuad, N.A.N. 2010. The effects of soil burial degredationof oil palm trunk fiber-filled recycled polypropylene composite. J. Reinforced Plastic and Composites 29 (11): 1652-1663.

Aryafatta, 2008. http://repository.usu.ac.id/bitstream/ 123456789/25729/5/, 16 oktober 2016.

Aulia, F., Marpongahtun, and S. Gea. 2013. Studi Penyediaan Nanokristal Selulosa Dari Tandan Kosong Sawit (TKS). J. Saintia Kim. 1(2).

Bahmid, N.A., K. Syamsu1, and A, Maddu. 2013. Production of Cellulose Acetate from Oil Palm Empty Fruit Bunches Cellulose. Chemical and Process Engineering Vol.17

Bentolila, M. 2013. Influence of Flow Parameters: Application in Scale-Up Processes in Chemical and Biological Systems. Dissertation, Hebrew University of Jerusalem

Brennan, L. and Owende, P., 2010. Biofuels from microalgae: a review of technologies for production, processing, and extractions of biofuels and co-products. Ren. Sustain. Energy Rev. 14, 557–577.

Buckle, K.A., Edwards, R.A. and Wouton, M. 2007. Ilmu Pangan. Terjemahan Food Science oleh Purnomo H dan Adiono. Universitas Indonesia Press, Jakarta.

Carvalho. L.G., Modesto, L.F.A., Aranda, D.A.G., and N. Pereira Jr. 2016. 2G Ethanol Production from Palm Lignocellulosic Biomass. J.Advan.Bio-technol. 6(1).

Dammer et al., Sustainable First and Second Generation Bioethanol for Europe, file:///C:/Users/ASUS/ Desktop/2017_Lokakarya%20Majlis%20Penilai/17-09-22-sust-bioethanol-long-version.pdf, 1 Oktober 2017.

Ditjen Perkebunan, Statistika Perkebunan Indonesia 2014-2016: Kelapa Sawit, Kementerian Pertanian, 2016.

Ewulonu, C.M. and Igwe, I.O. 2012. Properties of Oil Palm Empty Fruit Bunch Fibre Filled High Density Polyethylene, Int. J. Eng. and Technol, 3(6).

Gong, C.S. and Tsao, G.T., 2010. Cellulose and biosynthesis regulation. Annual Report Fermentation Process, Academic Press, New York, pp. 75-89.

Hasibuan, S and Nazir, N. 2017. The development strategy of sustainable bioethanol industry on iconic Sumba Island, Eastern Indonesia. International Journal on Advanced Science Engineering Informtion Technology, 7(1): 276-283.

Haetami, K., Abun, Y., and Mulyani. 2008. Studi Pembuatan ProbiotikBAS (Bacillus licheniformis, Aspergillus niger, and Saccharomyces cerevisiae) Sebagai Feed Suplement serta Implikasinya Terhadap Pertumbuhan Ikan Nila Merah. Laporan Penelitian. Fakultas Perikanan dan Ilmu Kelautan. Universitas Padjajaran. Bandung.

Hapsari, M.A., A, Pramashinta, and A, Purbasari. 2013. Pembuatan Bioetanol Dari Singkong Karet (Manihot glaziovii) Untuk Bahan Bakar Kompor Rumah Tangga Sebagai Upaya Mempercepat Konversi Minyak Tanah Ke Bahan Bakar Nabati. J.Tek.Kim.Ind. 2(2): 240-245.

Howard, R.L.I., Abotsi, E., Jansen Van Rensburg, E. L. I. and Howard, S. 2003. Lignocellulose biotechnology: issues of bioconversion and enzyme production. Review. African J.Biotechnol. 2 (12): 602-619.

Hoyer, K., M. Galbe., and G. Zacchi. 2010. Effects of enzyme feeding strategy on ethanol yield in fed-batch simultaneous saccharification and fermentation of spruce at high dry matter. Biotechnol biofuels. 3: 14 – 25. 1

Isroi, R. Millati., S. Syamsiah., C. Niklasson., M.N. Cahyanto., K. Lundquist., M.J. Taherzadeh. 2011. Biological pretreatment of lignocelluloses with white-rot fungi and its applications: A review. BioResources. 6: 5224– 5259.

Ka Ming, Ng. and Wibono, C., 2003. Beyond Process Design: "The emergence of a Process Development Focus"", Korean J. Chem. Eng., 20(5): 791-798.

Kementerian Perindustrin. 2009. Roadmap Industri Pengolahan CPO. Ditjen Industri Agro dan Kimia. Jakarta.

Kim, J. M. J. W Park, and C. H. Kim. 2012. Sequential acid-alkali pretreatment of oil palm empty fruit bunch fibres,” Bioresource Technology, 109: 229-233.

Larry Cooley and Rajani R. Ved. 2012. Scaling Up—From Vision to Largeâ€Scale Change. A Management Framework for Practitioners. MSI, Wahington DC.

Lee, H. V., S. B. A. Hamid., dan S. K. Zain. 2014. Conversion of lignocellulosic biomass to nanocellulose: structure and chemical process. The Scientific World Journal.

Lili Z, Xiliang Z., Jie X., Xunmin O., Shiyan C., and Maorong Wu. 2015. Techno-economic analysis of bioethanol production from lignocellulosic biomass in China: dilute-acid pretreatment and enzymatic hydrolysis of corn stover. Energies 8: 4096-4117.

Lim M.H. and Joseph. 2010. A case study on palm empty fruit bunch as energy feedstock. SEGi Review, 3(2).

Lim S. H., D. Ibrahim and I. C. Omar. 2012. Oil palm frond for the production of bioethanol. Int. J. Biochem. and Biotechnol. 1(1).

Lynd LR, Van Zyl WH, McBride JE, Laser M. 2005. Consolidated bioprocessing of cellulosic biomass: An update. Curr. Opin. Biotechnol, 16: 577-583

Mergner, R., R. Janssen., D. Rutz., I. de Bari., F. Sissot., D. Chiaramonti., A. Giovannini., S. Pescarolo., and R. Nistri. 2013. Lignocellulosic Ethanol Process and Demonstration. A Handbook Part I. WIP Renewable Energies. Munich.

Najafpour, G., A. Ideris, S. Salmanpour, M. Norouzi., and S.Iran. 2007. Acid Hydrolysis Of Pretreated Palm Oil Lignocellulosic Wastes. IJE Transact. B: Applications, 20(2).

Ningsih, Y.A., K.R. Lubis, and R. Moeksin. 2012. Pembuatan bioetanol dari tandan kosong kelapa sawit (TKKS) dengan metode hidrolisis asam dan fermentasi. J.Chem.Eng.Univ. Sriwijaya. 18(1).

Ojokoh, A.O. and R.E. Uzeh. 2005. Production of Saccharomyces cerevisiae biomass in Papaya Extract Medium. African Journal of Biotechnology. 4 (11): 1281-1284.

Olofsson et al,. 2008. A Short Review on SSF- An Interesting Process Option for Ethanol Production from Lignocellulosic Feedstock. BioMed Central Ltd.

Piarpuzan, D., J. A Quintero, and C. A. Cardona. 2011. Empty fruit bunches from oil palm as a potential raw material for fuel ethanol production, Biomass Bioenginering, 35: 1130-1137.

Piccolo, C and F. Bezzo. 2007. Ethanol from lignocellulosic biomass: a comparison between conversion technologies. 17th European Symposium on Computer Aided Process Engineering – ESCAPE17

Remli, N.A.M., U. K. Md Shah., R. Mohamad., and S. Abd Aziz. 2014. Effect of Chemical and Thermal Pretreatments On The Enzymatic Saccharification Of Rice Straw For Sugar Production. BioResources. 9 (1): 510–522.

Rana, V., A. D. Eckard., and B. K. Ahring. 2014. Comparison of SHF and SSF of Wet Exploded Corn Stover And Loblolly Pine Using In-House Enzymes Produced From T. reesei RUT C30 and A. saccharolyticus. SpringerPlus, 3 (1): 516.

Richana, N., C. Winarti, T. Hidayat, and B. Prastowo. 2015. Hydrolysis of Empty Fruit Bunches of Palm Oil (Elaeis Guineensis Jacq.) by Chemical, Physical, and Enzymatic Methods for Bioethanol Production. Int. J. Chem. Eng. and Appl, 6(6).

Samsudin, M. S. U. Kalsom, H. Zainudin, S. A. Aziz, S. M. M. Kamal, Y. Shirai, and M. A. Hassan. 2012. Effect of steam pretreatment on oil palm empty fruit bunch for the production of sugars. J. Biomass and Bioenergy, 36: 280-288,

Taherzadeh, M.J. and K. Karimi. 2008. Pretreatment of lignocellulosic wastes to improve ethanol and biogas production: a review. Int J Mol Sci. 9(9): 1621–1651.

Tsoutsos, T. and D. Bethanis. 2011. Optimization of the dilute acid hydrolyzator for cellulose-to-bioethanol saccharification. Energies 2011, 4

Wahyudi, T. Supriyanto., Abdullah, Widayat, Hadiyanto. 2010. Proses Produksi Etanol oleh Saccharomyces cerevisiae dengan Operasi Kontinyu pada Kondisi Vakum. Seminar Rekayas Kimia dan Proses 2010. Fakultas Teknik, Universitas Diponegoro, Semarang. 15: 1-6.

URL : http://ieomsociety.org/ieom2018/proceedings/

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Detail Karya Ilmiah Dosen

Sawarni Hasibuan, Hermawan

Judul	:	Scaling up Model for Developing Second-Generation (2G) Bioethanol by using Palm Empty Fruit Bunches Feedstock
Abstrak	:	As the country with the largest palm oil production in the world, the potential of lignocellulose waste like an empty fruit bunch produced by Indonesia is huge. Utilization of empty fruit bunch feedstock into second-generation (2G) bioethanol on a pilot scale is quite extensive. 2G bioethanol is also generally recognized as a promising market potential because of its less impact on the environment, however, the production cost is still rather high and the development of a commercially competitive process for 2G technology poses a challenge. This research attempts to investigate the model of scaling up of 2G bioethanol production to accelerate commercialization by integrating the well-established sucrose-tobioethanol process from palm oil lignocellulose feedstock. The case of scaling up to be calculated for a chemical pathway of bioethanol production with productivity consideration. Scaling up shows some of the unit process shall complete the basic step in laboratories scale. The supporting process must develop in pretreatment step likes empty fruit bunch washing, drying, and mechanical tearing. The additional process in hydrolysis step is filtering and evaporation glucose liquor until appropriate concentration. The distillation step develops for industrial scale according to alternatives products such as ethanol for solvent, pharmaceutical grade ethanol, or biofuels. The industrial-scale model estimate to produce 18.6 KL/days of bioethanol (ethanol content of 99.6%) need to support at least three crude palm oil plant with capacities 30-45 ton empty fruit bunch feedstock/hour. The model calculated empty fruit bunch feedstock about 600 ton/day.
Tahun	:	2018	Media Publikasi	:	Seminar Internasional
Kategori	:	Prosiding	No/Vol/Tahun	:	- / - / 2018
ISSN/ISBN	:	2169-8767
PTN/S	:	Universitas MercuBuana Jakarta dan Universitas Pakuan Bogor	Program Studi	:	ILMU KOMPUTER
Bibliography	:	Abdul Khalil, H.P.S., Poh, B.T., Jawaid, M., Ridzuan, R., Said, M.R., Achmad, F., and Fuad, N.A.N. 2010. The effects of soil burial degredationof oil palm trunk fiber-filled recycled polypropylene composite. J. Reinforced Plastic and Composites 29 (11): 1652-1663. Aryafatta, 2008. http://repository.usu.ac.id/bitstream/ 123456789/25729/5/, 16 oktober 2016. Aulia, F., Marpongahtun, and S. Gea. 2013. Studi Penyediaan Nanokristal Selulosa Dari Tandan Kosong Sawit (TKS). J. Saintia Kim. 1(2). Bahmid, N.A., K. Syamsu1, and A, Maddu. 2013. Production of Cellulose Acetate from Oil Palm Empty Fruit Bunches Cellulose. Chemical and Process Engineering Vol.17 Bentolila, M. 2013. Influence of Flow Parameters: Application in Scale-Up Processes in Chemical and Biological Systems. Dissertation, Hebrew University of Jerusalem Brennan, L. and Owende, P., 2010. Biofuels from microalgae: a review of technologies for production, processing, and extractions of biofuels and co-products. Ren. Sustain. Energy Rev. 14, 557–577. Buckle, K.A., Edwards, R.A. and Wouton, M. 2007. Ilmu Pangan. Terjemahan Food Science oleh Purnomo H dan Adiono. Universitas Indonesia Press, Jakarta. Carvalho. L.G., Modesto, L.F.A., Aranda, D.A.G., and N. Pereira Jr. 2016. 2G Ethanol Production from Palm Lignocellulosic Biomass. J.Advan.Bio-technol. 6(1). Dammer et al., Sustainable First and Second Generation Bioethanol for Europe, file:///C:/Users/ASUS/ Desktop/2017_Lokakarya%20Majlis%20Penilai/17-09-22-sust-bioethanol-long-version.pdf, 1 Oktober 2017. Ditjen Perkebunan, Statistika Perkebunan Indonesia 2014-2016: Kelapa Sawit, Kementerian Pertanian, 2016. Ewulonu, C.M. and Igwe, I.O. 2012. Properties of Oil Palm Empty Fruit Bunch Fibre Filled High Density Polyethylene, Int. J. Eng. and Technol, 3(6). Gong, C.S. and Tsao, G.T., 2010. Cellulose and biosynthesis regulation. Annual Report Fermentation Process, Academic Press, New York, pp. 75-89. Hasibuan, S and Nazir, N. 2017. The development strategy of sustainable bioethanol industry on iconic Sumba Island, Eastern Indonesia. International Journal on Advanced Science Engineering Informtion Technology, 7(1): 276-283. Haetami, K., Abun, Y., and Mulyani. 2008. Studi Pembuatan ProbiotikBAS (Bacillus licheniformis, Aspergillus niger, and Saccharomyces cerevisiae) Sebagai Feed Suplement serta Implikasinya Terhadap Pertumbuhan Ikan Nila Merah. Laporan Penelitian. Fakultas Perikanan dan Ilmu Kelautan. Universitas Padjajaran. Bandung. Hapsari, M.A., A, Pramashinta, and A, Purbasari. 2013. Pembuatan Bioetanol Dari Singkong Karet (Manihot glaziovii) Untuk Bahan Bakar Kompor Rumah Tangga Sebagai Upaya Mempercepat Konversi Minyak Tanah Ke Bahan Bakar Nabati. J.Tek.Kim.Ind. 2(2): 240-245. Howard, R.L.I., Abotsi, E., Jansen Van Rensburg, E. L. I. and Howard, S. 2003. Lignocellulose biotechnology: issues of bioconversion and enzyme production. Review. African J.Biotechnol. 2 (12): 602-619. Hoyer, K., M. Galbe., and G. Zacchi. 2010. Effects of enzyme feeding strategy on ethanol yield in fed-batch simultaneous saccharification and fermentation of spruce at high dry matter. Biotechnol biofuels. 3: 14 – 25. 1 Isroi, R. Millati., S. Syamsiah., C. Niklasson., M.N. Cahyanto., K. Lundquist., M.J. Taherzadeh. 2011. Biological pretreatment of lignocelluloses with white-rot fungi and its applications: A review. BioResources. 6: 5224– 5259. Ka Ming, Ng. and Wibono, C., 2003. Beyond Process Design: "The emergence of a Process Development Focus"", Korean J. Chem. Eng., 20(5): 791-798. Kementerian Perindustrin. 2009. Roadmap Industri Pengolahan CPO. Ditjen Industri Agro dan Kimia. Jakarta. Kim, J. M. J. W Park, and C. H. Kim. 2012. Sequential acid-alkali pretreatment of oil palm empty fruit bunch fibres,” Bioresource Technology, 109: 229-233. Larry Cooley and Rajani R. Ved. 2012. Scaling Up—From Vision to Largeâ€Scale Change. A Management Framework for Practitioners. MSI, Wahington DC. Lee, H. V., S. B. A. Hamid., dan S. K. Zain. 2014. Conversion of lignocellulosic biomass to nanocellulose: structure and chemical process. The Scientific World Journal. Lili Z, Xiliang Z., Jie X., Xunmin O., Shiyan C., and Maorong Wu. 2015. Techno-economic analysis of bioethanol production from lignocellulosic biomass in China: dilute-acid pretreatment and enzymatic hydrolysis of corn stover. Energies 8: 4096-4117. Lim M.H. and Joseph. 2010. A case study on palm empty fruit bunch as energy feedstock. SEGi Review, 3(2). Lim S. H., D. Ibrahim and I. C. Omar. 2012. Oil palm frond for the production of bioethanol. Int. J. Biochem. and Biotechnol. 1(1). Lynd LR, Van Zyl WH, McBride JE, Laser M. 2005. Consolidated bioprocessing of cellulosic biomass: An update. Curr. Opin. Biotechnol, 16: 577-583 Mergner, R., R. Janssen., D. Rutz., I. de Bari., F. Sissot., D. Chiaramonti., A. Giovannini., S. Pescarolo., and R. Nistri. 2013. Lignocellulosic Ethanol Process and Demonstration. A Handbook Part I. WIP Renewable Energies. Munich. Najafpour, G., A. Ideris, S. Salmanpour, M. Norouzi., and S.Iran. 2007. Acid Hydrolysis Of Pretreated Palm Oil Lignocellulosic Wastes. IJE Transact. B: Applications, 20(2). Ningsih, Y.A., K.R. Lubis, and R. Moeksin. 2012. Pembuatan bioetanol dari tandan kosong kelapa sawit (TKKS) dengan metode hidrolisis asam dan fermentasi. J.Chem.Eng.Univ. Sriwijaya. 18(1). Ojokoh, A.O. and R.E. Uzeh. 2005. Production of Saccharomyces cerevisiae biomass in Papaya Extract Medium. African Journal of Biotechnology. 4 (11): 1281-1284. Olofsson et al,. 2008. A Short Review on SSF- An Interesting Process Option for Ethanol Production from Lignocellulosic Feedstock. BioMed Central Ltd. Piarpuzan, D., J. A Quintero, and C. A. Cardona. 2011. Empty fruit bunches from oil palm as a potential raw material for fuel ethanol production, Biomass Bioenginering, 35: 1130-1137. Piccolo, C and F. Bezzo. 2007. Ethanol from lignocellulosic biomass: a comparison between conversion technologies. 17th European Symposium on Computer Aided Process Engineering – ESCAPE17 Remli, N.A.M., U. K. Md Shah., R. Mohamad., and S. Abd Aziz. 2014. Effect of Chemical and Thermal Pretreatments On The Enzymatic Saccharification Of Rice Straw For Sugar Production. BioResources. 9 (1): 510–522. Rana, V., A. D. Eckard., and B. K. Ahring. 2014. Comparison of SHF and SSF of Wet Exploded Corn Stover And Loblolly Pine Using In-House Enzymes Produced From T. reesei RUT C30 and A. saccharolyticus. SpringerPlus, 3 (1): 516. Richana, N., C. Winarti, T. Hidayat, and B. Prastowo. 2015. Hydrolysis of Empty Fruit Bunches of Palm Oil (Elaeis Guineensis Jacq.) by Chemical, Physical, and Enzymatic Methods for Bioethanol Production. Int. J. Chem. Eng. and Appl, 6(6). Samsudin, M. S. U. Kalsom, H. Zainudin, S. A. Aziz, S. M. M. Kamal, Y. Shirai, and M. A. Hassan. 2012. Effect of steam pretreatment on oil palm empty fruit bunch for the production of sugars. J. Biomass and Bioenergy, 36: 280-288, Taherzadeh, M.J. and K. Karimi. 2008. Pretreatment of lignocellulosic wastes to improve ethanol and biogas production: a review. Int J Mol Sci. 9(9): 1621–1651. Tsoutsos, T. and D. Bethanis. 2011. Optimization of the dilute acid hydrolyzator for cellulose-to-bioethanol saccharification. Energies 2011, 4 Wahyudi, T. Supriyanto., Abdullah, Widayat, Hadiyanto. 2010. Proses Produksi Etanol oleh Saccharomyces cerevisiae dengan Operasi Kontinyu pada Kondisi Vakum. Seminar Rekayas Kimia dan Proses 2010. Fakultas Teknik, Universitas Diponegoro, Semarang. 15: 1-6.
URL	:	http://ieomsociety.org/ieom2018/proceedings/